Consider this XML
Suppose you want to get count of student ids. You can use SQL to get the count as follows.
declare @xml XML;
set @xml ='<Students>
<Student>
<Id>001</Id>
<Fname>Leesa</Fname>
<Sname>Humpry</Sname>
</Student>
<Student>
<Id>002</Id>
<Fname>Clara</FName>
<Sname>Margrette</Sname>
</Student>
</Students>';
select @xml.value('count(/Students/Student/Id)', 'INT') AS 'Count'
Cheers
Samitha